ChemistryNEB 2082 (MCQs)

A compound 'Z' with molecular formula C3H4O4 is heated to produce compound 'Y' and CO2 gas. Heating of compound 'Y' with P2O5 forms compound 'X' and water molecule. Identify the compound 'X'. a)…

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A compound 'Z' with molecular formula is heated to produce compound 'Y' and gas. Heating of compound 'Y' with forms compound 'X' and water molecule. Identify the compound 'X'. a) Ethanoic acid b) Ethanoic anhydirde c) Methanoic anhydride d) Ethanal

Answer

The given molecular formula of compound Z is . When heated, it decomposes to form Y and gas. This suggests that Z is likely a dicarboxylic acid (since is released upon heating, indicating decarboxylation).

The only dicarboxylic acid with the formula is malonic acid (). Upon heating, malonic acid decomposes to form ethanoic acid (acetic acid, ) and :

C3H4O4malonic acidheatacetic acidacetic acid+CO2
Decarboxylation of malonic acid (C₃H₄O₄) to form ethanoic acid (CH₃COOH) and CO₂

Thus, Y is ethanoic acid ().

When Y (ethanoic acid) is heated with (a dehydrating agent), it forms ethanoic anhydride () and water:

acetic acidacetic acidP₂O₅ (dehydrating agent)acetic anhydrideacetic anhydride+H2O
Dehydration of ethanoic acid (CH₃COOH) to form ethanoic anhydride ((CH₃CO)₂O) and water

Therefore, the compound X is ethanoic anhydride.

Answer: b) Ethanoic anhydride

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