ChemistryNEB 2076 (old course)

State the first law of thermodynamics.

2

Answer

The First Law of Thermodynamics states that energy can neither be created nor destroyed, but it can be converted from one form to another. Mathematically, it is expressed as:

where:

  • = change in internal energy of the system,
  • = heat added to the system (positive if absorbed, negative if released),
  • = work done on the system (positive if work is done on the system, negative if work is done by the system).

This law is essentially a restatement of the law of conservation of energy applied to thermodynamic processes. It establishes a relationship between the internal energy of a system and the heat and work interactions with its surroundings. The law applies to all types of energy transformations, whether in chemical reactions, physical changes, or mechanical processes.

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