ChemistryNEB 2081 (MCQs)

Which of the following molecules does not act as a ligand ? a) CO2 b) NH3 c) H2O d) CO

1

Answer

A ligand is a molecule or ion that donates a pair of electrons to a central metal ion to form a coordinate bond. Ligands must have at least one lone pair of electrons or a π-electron system capable of donating electron density.

  • and are classic examples of ligands because they have lone pairs on nitrogen and oxygen, respectively.
  • is also a ligand due to its π-electron system that can back-bond with metal centers.
  • , however, is linear and symmetric with no lone pairs on carbon or oxygen. It lacks a suitable electron pair to donate to a metal ion, making it non-coordinating under normal conditions.

Thus, the correct answer is (a) .

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