ChemistryNEB 2076 (old course)

Define reducing agent giving an example. Balance the following redox reaction by oxidation number or ion electron method: [1+4] MnO 2 + HCl MnCl 2 + Cl 2 + H 2O

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Answer

Model Answer

1. Definition of Reducing Agent with Example

A reducing agent is a substance that loses electrons (or increases the oxidation state of another species) in a redox reaction. It itself gets oxidized while reducing another species. Reducing agents are electron donors and typically contain elements in a low oxidation state.

Example: In the reaction between zinc and copper sulfate, Zinc () acts as a reducing agent because it loses electrons to reduce to while itself getting oxidized to .


2. Balancing the Redox Reaction:

Method: Ion-electron method (half-reaction method)

Step 1: Assign oxidation numbers and identify changes

  • in : → in (reduction)
  • in : → in (oxidation)

Step 2: Write half-reactions

  • Oxidation half-reaction (Cl⁻ → Cl₂):

  • Reduction half-reaction (Mn⁴⁺ → Mn²⁺):

Step 3: Balance electrons and combine

  • Multiply oxidation half-reaction by 1 and reduction half-reaction by 1 to balance electrons.
  • Combine:

Step 4: Add spectator ions (H⁺ and Cl⁻ from HCl)

  • provides and .
  • Final balanced equation:

Verification:

  • Mn: → (balanced)
  • Cl: → (balanced)
  • H and O: Balanced with .

Final balanced equation:

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