ChemistryNEB 2076 (old course)

What is meant by para hydrogen ? How is it converted into ortho hydrogen ? [1+1]

2

Answer

Para-hydrogen refers to the molecular form of hydrogen () in which the nuclear spins of the two hydrogen atoms are antiparallel (paired). This means the spins of the two protons are in opposite directions, resulting in a net spin quantum number . Para-hydrogen is the lower-energy state and is more stable at lower temperatures.

Conversion to ortho-hydrogen occurs when the nuclear spins of the two hydrogen atoms become parallel (both spins aligned in the same direction), giving a net spin quantum number . This conversion can be achieved by:

  • Catalytic conversion using catalysts like activated carbon, iron oxide, or platinum at elevated temperatures.
  • Thermal equilibrium: At room temperature, hydrogen exists as a 3:1 mixture of ortho- and para-hydrogen. Cooling the gas shifts the equilibrium toward para-hydrogen, while heating favors ortho-hydrogen. The conversion is slow in the absence of a catalyst.

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